| 1. Round | 19/08/2024 | Villarreal CF | - | Atlético Madrid | 2:2 | ||||
| 4. Round | 31/08/2024 | Valencia CF | - | Villarreal CF | 1:1 | ||||
| 5. Round | 14/09/2024 | RCD Mallorca | - | Villarreal CF | 1:2 | ||||
| 6. Round | 22/09/2024 | Villarreal CF | - | FC Barcelona | 1:5 | ||||
| 7. Round | 26/09/2024 | Espanyol Barcelona | - | Villarreal CF | 1:2 |  |
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| 8. Round | 30/09/2024 | Villarreal CF | - | UD Las Palmas | 3:1 | ||||
| 9. Round | 05/10/2024 | Real Madrid | - | Villarreal CF | 2:0 | ||||
| 10. Round | 20/10/2024 | Villarreal CF | - | Getafe CF | 1:1 | ||||
| 11. Round | 26/10/2024 | Real Valladolid | - | Villarreal CF | 1:2 | ||||
| 14. Round | 24/11/2024 | CA Osasuna | - | Villarreal CF | 2:2 | ||||
| 20. Round | 20/01/2025 | Villarreal CF | - | RCD Mallorca | 4:0 |
Spain