| 3. Round | 27/09/2020 | Real Valladolid | - | RC Celta | 1:1 | ||||
| 4. Round | 30/09/2020 | Real Madrid | - | Real Valladolid | 1:0 | ||||
| 6. Round | 18/10/2020 | SD Huesca | - | Real Valladolid | 2:2 | ||||
| 7. Round | 25/10/2020 | Real Valladolid | - | CD Alavés | 0:2 | ||||
| 8. Round | 02/11/2020 | Villarreal CF | - | Real Valladolid | 2:0 |  |
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| 9. Round | 08/11/2020 | Real Valladolid | - | Athletic Club | 2:1 | |
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| 14. Round | 19/12/2020 | Sevilla FC | - | Real Valladolid | 1:1 |  |
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| 16. Round | 29/12/2020 | Cádiz CF | - | Real Valladolid | 0:0 |
Spain
