| 1. Round | 28/09/1941 | FC Barcelona | - | Hércules CF | 4:4 |  |
|||
| 3. Round | 12/10/1941 | Sevilla FC | - | Hércules CF | 7:2 | |
|||
| 4. Round | 19/10/1941 | Hércules CF | - | Real Oviedo | 4:1 | ||||
| 5. Round | 26/10/1941 | CD Castellón | - | Hércules CF | 4:0 | ||||
| 8. Round | 16/11/1941 | RC Celta | - | Hércules CF | 4:1 | ||||
| 9. Round | 23/11/1941 | Hércules CF | - | Real Madrid | 1:2 | ||||
| 11. Round | 07/12/1941 | Hércules CF | - | Real Sociedad | 3:1 | ||||
| 25. Round | 29/03/1942 | Hércules CF | - | Granada CF | 2:2 | |
|||
| 26. Round | 05/04/1942 | Athletic Club | - | Hércules CF | 2:2 |
Spain