| 11. Round | 11/11/2012 | Real Valladolid | - | Valencia CF | 1:1 | ||||
| 16. Round | 17/12/2012 | Deportivo La Coruña | - | Real Valladolid | 0:0 | ||||
| 18. Round | 06/01/2013 | RC Celta | - | Real Valladolid | 3:1 |
| 11. Round | 11/11/2012 | Real Valladolid | - | Valencia CF | 1:1 | ||||
| 16. Round | 17/12/2012 | Deportivo La Coruña | - | Real Valladolid | 0:0 | ||||
| 18. Round | 06/01/2013 | RC Celta | - | Real Valladolid | 3:1 |
| Rubén Peña Jiménez | |
| Born: | 18.07.1991 |
| Place of birth: |
Ávila, 
Spain |
| Nationality: |
Spain
|
| Height: | 170 cm |
| Weight: | 65 kg |
| Position(s): | Right Back Right Midfielder |
| Foot: | right |