| 1. Round | 30/08/1985 | CA Osasuna | - | Athletic Club | 0:1 | ||||
| 2. Round | 03/09/1985 | Sevilla FC | - | CA Osasuna | 1:0 | ||||
| 3. Round | 07/09/1985 | CA Osasuna | - | Hércules CF | 1:0 | ||||
| 4. Round | 13/09/1985 | FC Barcelona | - | CA Osasuna | 2:2 |  |
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| 7. Round | 13/10/1985 | CA Osasuna | - | Real Madrid | 0:1 | ||||
| 28. Round | 08/03/1986 | Real Betis | - | CA Osasuna | 1:0 | ||||
| 30. Round | 21/03/1986 | Espanyol Barcelona | - | CA Osasuna | 0:1 | ||||
| 32. Round | 05/04/1986 | Real Zaragoza | - | CA Osasuna | 1:1 | ||||
| 34. Round | 18/04/1986 | UD Las Palmas | - | CA Osasuna | 0:0 |
Spain