| 1. Round | 16/09/1962 | Athletic Club | - | FC Barcelona | 2:3 | ||||
| 2. Round | 23/09/1962 | FC Barcelona | - | Real Betis | 1:0 | ||||
| 3. Round | 30/09/1962 | Real Madrid | - | FC Barcelona | 2:0 | ||||
| 4. Round | 07/10/1962 | FC Barcelona | - | Deportivo La Coruña | 5:2 | ||||
| 5. Round | 14/10/1962 | FC Barcelona | - | CD Málaga | 4:0 | ||||
| 9. Round | 11/11/1962 | FC Barcelona | - | Valencia CF | 1:1 | ||||
| 10. Round | 18/11/1962 | Sevilla FC | - | FC Barcelona | 1:0 | ||||
| 11. Round | 09/12/1962 | FC Barcelona | - | Atlético Madrid | 0:0 | ||||
| 12. Round | 16/12/1962 | Real Zaragoza | - | FC Barcelona | 2:1 | ||||
| 13. Round | 23/12/1962 | FC Barcelona | - | Córdoba CF | 2:1 | ||||
| 14. Round | 30/12/1962 | CA Osasuna | - | FC Barcelona | 3:1 | ||||
| 15. Round | 06/01/1963 | FC Barcelona | - | RCD Mallorca | 1:1 | ||||
| 16. Round | 13/01/1963 | FC Barcelona | - | Athletic Club | 0:0 | ||||
| 17. Round | 20/01/1963 | Real Betis | - | FC Barcelona | 1:1 | ||||
| 18. Round | 27/01/1963 | FC Barcelona | - | Real Madrid | 1:5 |
Spain