| 13. Round | 13/12/2020 | FC Barcelona | - | Levante UD | 1:0 | ||||
| 15. Round | 22/12/2020 | Real Valladolid | - | FC Barcelona | 0:3 | ||||
| 18. Round | 09/01/2021 | Granada CF | - | FC Barcelona | 0:4 | ||||
| 20. Round | 24/01/2021 | Elche CF | - | FC Barcelona | 0:2 | ||||
| 21. Round | 31/01/2021 | FC Barcelona | - | Athletic Club | 2:1 | ||||
| 22. Round | 07/02/2021 | Real Betis | - | FC Barcelona | 2:3 | ||||
| 23. Round | 13/02/2021 | FC Barcelona | - | CD Alavés | 5:1 | ||||
| 1. Round | 24/02/2021 | FC Barcelona | - | Elche CF | 3:0 | ||||
| 25. Round | 27/02/2021 | Sevilla FC | - | FC Barcelona | 0:2 | ||||
| 26. Round | 06/03/2021 | CA Osasuna | - | FC Barcelona | 0:2 |  |
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| 31. Round | 22/04/2021 | FC Barcelona | - | Getafe CF | 5:2 | ||||
| 33. Round | 29/04/2021 | FC Barcelona | - | Granada CF | 1:2 | ||||
| 38. Round | 22/05/2021 | SD Eibar | - | FC Barcelona | 0:1 |
Cameroon
