| 7. Round | 04/11/1945 | Sporting Gijón | - | Espanyol Barcelona | 4:1 | ||||
| 8. Round | 18/11/1945 | CD Alcoyano | - | Sporting Gijón | 4:1 |  |
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| 9. Round | 25/11/1945 | Sporting Gijón | - | Atlético Aviación | 3:2 | |
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| 10. Round | 02/12/1945 | Athletic Club | - | Sporting Gijón | 2:3 | |
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| 12. Round | 16/12/1945 | Real Murcia | - | Sporting Gijón | 1:0 | ||||
| 13. Round | 30/12/1945 | Sporting Gijón | - | Real Oviedo | 1:0 | ||||
| 14. Round | 06/01/1946 | Sporting Gijón | - | FC Barcelona | 2:0 | ||||
| 15. Round | 13/01/1946 | Hércules CF | - | Sporting Gijón | 2:1 | ||||
| 17. Round | 27/01/1946 | CD Castellón | - | Sporting Gijón | 2:0 | ||||
| 18. Round | 03/02/1946 | Sporting Gijón | - | Sevilla FC | 1:2 | ||||
| 20. Round | 17/02/1946 | Espanyol Barcelona | - | Sporting Gijón | 2:2 | |
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| 21. Round | 24/02/1946 | Sporting Gijón | - | CD Alcoyano | 1:1 | |
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| 22. Round | 03/03/1946 | Atlético Aviación | - | Sporting Gijón | 2:0 | ||||
| 23. Round | 10/03/1946 | Sporting Gijón | - | Athletic Club | 0:0 | ||||
| 24. Round | 17/03/1946 | Valencia CF | - | Sporting Gijón | 1:1 | ||||
| 25. Round | 24/03/1946 | Sporting Gijón | - | Real Murcia | 0:2 | ||||
| 26. Round | 31/03/1946 | Real Oviedo | - | Sporting Gijón | 2:2 |
Spain