| 5. Round | 16/10/2022 | Alhama CF [Women] | - | Valencia CF [Women] | 0:1 | ||||
| 7. Round | 30/10/2022 | Villarreal CF [Women] | - | Valencia CF [Women] | 1:1 |  |
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| 1. Round | 02/11/2022 | Valencia CF [Women] | - | Real Betis [Women] | 3:0 | ||||
| 8. Round | 05/11/2022 | Valencia CF [Women] | - | Athletic Club [Women] | 1:2 | |
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| 9. Round | 19/11/2022 | Valencia CF [Women] | - | Levante UD [Women] | 4:2 | ||||
| 10. Round | 27/11/2022 | UDG Tenerife Sur [Women] | - | Valencia CF [Women] | 1:0 | ||||
| 11. Round | 04/12/2022 | Valencia CF [Women] | - | Atlético Madrid [Women] | 0:1 | ||||
| 12. Round | 10/12/2022 | Madrid CFF [Women] | - | Valencia CF [Women] | 3:1 | |
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| 14. Round | 07/01/2023 | CD Alavés [Women] | - | Valencia CF [Women] | 4:1 | ||||
| 16. Round | 24/01/2023 | Valencia CF [Women] | - | Villarreal CF [Women] | 2:0 | |
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| 27. Round | 29/04/2023 | Valencia CF [Women] | - | CD Alavés [Women] | 2:1 | ||||
| 28. Round | 07/05/2023 | Levante UD [Women] | - | Valencia CF [Women] | 1:1 | ||||
| 29. Round | 14/05/2023 | Valencia CF [Women] | - | Madrid CFF [Women] | 0:2 |
Spain