| 2. Round | 31/08/2014 | Villarreal CF | - | FC Barcelona | 0:1 |  |
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| 3. Round | 13/09/2014 | FC Barcelona | - | Athletic Club | 2:0 | ||||
| 4. Round | 21/09/2014 | Levante UD | - | FC Barcelona | 0:5 | |
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| 5. Round | 24/09/2014 | Málaga CF | - | FC Barcelona | 0:0 | ||||
| 6. Round | 27/09/2014 | FC Barcelona | - | Granada CF | 6:0 | ||||
| 7. Round | 04/10/2014 | Rayo Vallecano | - | FC Barcelona | 0:2 | ||||
| 8. Round | 18/10/2014 | FC Barcelona | - | SD Eibar | 3:0 |
Spain
