| 23. Round | 08/02/2025 | Athletic Club | - | Girona FC | 3:0 | ||||
| 24. Round | 16/02/2025 | Espanyol Barcelona | - | Athletic Club | 1:1 | ||||
| 25. Round | 23/02/2025 | Athletic Club | - | Real Valladolid | 7:1 |  |
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| 26. Round | 01/03/2025 | Atlético Madrid | - | Athletic Club | 1:0 | ||||
| 27. Round | 09/03/2025 | Athletic Club | - | RCD Mallorca | 1:1 | ||||
| 28. Round | 16/03/2025 | Sevilla FC | - | Athletic Club | 0:1 | ||||
| 29. Round | 30/03/2025 | Athletic Club | - | CA Osasuna | 0:0 | ||||
| 30. Round | 06/04/2025 | Villarreal CF | - | Athletic Club | 0:0 | ||||
| 31. Round | 13/04/2025 | Athletic Club | - | Rayo Vallecano | 3:1 | ||||
| 32. Round | 20/04/2025 | Real Madrid | - | Athletic Club | 1:0 | ||||
| 33. Round | 23/04/2025 | Athletic Club | - | UD Las Palmas | 1:0 | ||||
| 34. Round | 04/05/2025 | Real Sociedad | - | Athletic Club | 0:0 | ||||
| 35. Round | 11/05/2025 | Athletic Club | - | CD Alavés | 1:0 | ||||
| 36. Round | 15/05/2025 | Getafe CF | - | Athletic Club | 0:2 | ||||
| 37. Round | 18/05/2025 | Valencia CF | - | Athletic Club | 0:1 | ||||
| 38. Round | 25/05/2025 | Athletic Club | - | FC Barcelona | 0:3 |
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