| 21. Round | 11/01/2014 | Royal Antwerp FC | - | Royal Mouscron-Péruwelz | 0:1 | ||||
| 22. Round | 19/01/2014 | Royal Mouscron-Péruwelz | - | Eendracht Aalst | 0:0 |  |
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| 23. Round | 25/01/2014 | KSK Heist | - | Royal Mouscron-Péruwelz | 1:2 | |
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| 24. Round | 01/02/2014 | Royal Mouscron-Péruwelz | - | ASV Geel | 2:1 | |
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| 25. Round | 08/02/2014 | Hoogstraten VV | - | Royal Mouscron-Péruwelz | 0:4 | ||||
| 26. Round | 14/02/2014 | KAS Eupen | - | Royal Mouscron-Péruwelz | 0:1 | ||||
| 27. Round | 01/03/2014 | Royal Mouscron-Péruwelz | - | AFC Tubize | 0:1 | ||||
| 28. Round | 08/03/2014 | Lommel United | - | Royal Mouscron-Péruwelz | 3:1 | ||||
| 29. Round | 15/03/2014 | Royal Mouscron-Péruwelz | - | CS Visé | 2:1 | |
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| 30. Round | 30/03/2014 | Excelsior Virton | - | Royal Mouscron-Péruwelz | 0:2 | ||||
| 31. Round | 05/04/2014 | Royal Mouscron-Péruwelz | - | Sint-Truidense VV | 1:1 |  |
France