| 5. Round | 06/10/1991 | FC Barcelona | - | Real Oviedo | 1:2 | ||||
| 8. Round | 02/11/1991 | CD Logroñés | - | FC Barcelona | 2:2 | ||||
| 9. Round | 09/11/1991 | FC Barcelona | - | CA Osasuna | 2:0 | ||||
| 10. Round | 16/11/1991 | Deportivo La Coruña | - | FC Barcelona | 0:4 | ||||
| 11. Round | 22/11/1991 | FC Barcelona | - | Valencia CF | 3:1 | ||||
| 12. Round | 29/11/1991 | Albacete | - | FC Barcelona | 1:1 | ||||
| 13. Round | 06/12/1991 | FC Barcelona | - | CD Tenerife | 5:3 | ||||
| 14. Round | 14/12/1991 | Real Burgos | - | FC Barcelona | 2:2 | ||||
| 16. Round | 04/01/1992 | RCD Mallorca | - | FC Barcelona | 1:2 | ||||
| 17. Round | 11/01/1992 | FC Barcelona | - | Real Valladolid | 2:1 | ||||
| 27. Round | 21/03/1992 | FC Barcelona | - | CD Logroñés | 1:0 | ||||
| 28. Round | 27/03/1992 | CA Osasuna | - | FC Barcelona | 0:0 | ||||
| 29. Round | 04/04/1992 | FC Barcelona | - | Deportivo La Coruña | 4:1 | ||||
| 30. Round | 10/04/1992 | Valencia CF | - | FC Barcelona | 1:0 |  |
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| 35. Round | 15/05/1992 | FC Barcelona | - | RCD Mallorca | 3:0 | |
Spain