| 2. Round | 11/10/2020 | Madrid CFF [Women] | - | Espanyol Barcelona [Women] | 0:1 | ||||
| 5. Round | 05/11/2020 | Athletic Club [Women] | - | Madrid CFF [Women] | 2:0 | ||||
| 9. Round | 22/11/2020 | Rayo Vallecano [Women] | - | Madrid CFF [Women] | 1:4 | ||||
| 7. Round | 09/12/2020 | Sporting de Huelva [Women] | - | Madrid CFF [Women] | 1:0 | ||||
| 13. Round | 22/12/2020 | Levante UD [Women] | - | Madrid CFF [Women] | 4:2 | ||||
| 32. Round | 06/06/2021 | FC Barcelona [Women] | - | Madrid CFF [Women] | 3:2 | ||||
| 33. Round | 19/06/2021 | Espanyol Barcelona [Women] | - | Madrid CFF [Women] | 3:3 | ||||
| 34. Round | 27/06/2021 | Madrid CFF [Women] | - | Real Betis [Women] | 2:2 |
Spain