| 2. Round | 15/09/2024 | Madrid CFF [Women] | - | Espanyol Barcelona [Women] | 2:1 | ||||
| 5. Round | 06/10/2024 | Espanyol Barcelona [Women] | - | SD Eibar [Women] | 2:1 | ||||
| 6. Round | 13/10/2024 | FC Barcelona [Women] | - | Espanyol Barcelona [Women] | 7:1 |  |
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| 7. Round | 19/10/2024 | Sevilla FC [Women] | - | Espanyol Barcelona [Women] | 1:0 | ||||
| 9. Round | 10/11/2024 | Espanyol Barcelona [Women] | - | Granada CF [Women] | 1:0 | ||||
| 15. Round | 19/01/2025 | Real Sociedad [Women] | - | Espanyol Barcelona [Women] | 4:1 | ||||
| 17. Round | 31/01/2025 | Real Madrid [Women] | - | Espanyol Barcelona [Women] | 5:0 | ||||
| 18. Round | 09/02/2025 | Espanyol Barcelona [Women] | - | FC Barcelona [Women] | 0:2 | ||||
| 24. Round | 29/03/2025 | Costa Adeje Tenerife [Women] | - | Espanyol Barcelona [Women] | 4:1 | ||||
| 26. Round | 19/04/2025 | Espanyol Barcelona [Women] | - | Levante Las Planas [Women] | 2:0 | ||||
| 27. Round | 26/04/2025 | SD Eibar [Women] | - | Espanyol Barcelona [Women] | 1:1 |
Colombia