| 1. Round | 04/09/1965 | Sevilla FC | - | Valencia CF | 1:1 | ||||
| 2. Round | 12/09/1965 | Valencia CF | - | CD Málaga | 1:0 | ||||
| 3. Round | 19/09/1965 | Athletic Club | - | Valencia CF | 1:0 | ||||
| 14. Round | 19/12/1965 | Real Zaragoza | - | Valencia CF | 2:0 | ||||
| 20. Round | 23/01/1966 | Valencia CF | - | FC Barcelona | 0:2 |
Spain