| 18. Round | 15/01/2005 | RAA La Louviére | - | Sporting Charleroi | 0:0 | ||||
| 19. Round | 22/01/2005 | Sporting Charleroi | - | Standard Liège | 0:0 | ||||
| 20. Round | 29/01/2005 | KVC Westerlo | - | Sporting Charleroi | 2:1 | ||||
| 23. Round | 19/02/2005 | Sporting Charleroi | - | RAEC Mons | 1:0 | ||||
| 25. Round | 12/03/2005 | Sporting Charleroi | - | Sint-Truidense VV | 0:0 | ||||
| 26. Round | 19/03/2005 | KSK Beveren | - | Sporting Charleroi | 1:2 | ||||
| 27. Round | 02/04/2005 | Sporting Charleroi | - | KAA Gent | 3:2 | ||||
| 30. Round | 24/04/2005 | Sporting Charleroi | - | Excelsior Mouscron | 2:0 | ||||
| 33. Round | 15/05/2005 | KRC Genk | - | Sporting Charleroi | 2:0 | ||||
| 34. Round | 21/05/2005 | Sporting Charleroi | - | Sporting Lokeren | 2:1 |  |
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France