| 23. Round | 14/01/2012 | Heart of Midlothian | - | St. Mirren FC | 5:2 | ||||
| 24. Round | 21/01/2012 | Inverness CT | - | Heart of Midlothian | 1:0 | ||||
| 25. Round | 08/02/2012 | Heart of Midlothian | - | Celtic FC | 0:4 | ||||
| 26. Round | 11/02/2012 | Kilmarnock FC | - | Heart of Midlothian | 1:1 |  |
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| 28. Round | 25/02/2012 | Heart of Midlothian | - | Dundee United | 0:2 |  |
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| 30. Round | 18/03/2012 | Heart of Midlothian | - | Hibernian FC | 2:0 | |
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| 31. Round | 24/03/2012 | St. Johnstone FC | - | Heart of Midlothian | 2:1 | ||||
| 32. Round | 31/03/2012 | Heart of Midlothian | - | Aberdeen FC | 3:0 | ||||
| 33. Round | 07/04/2012 | Dunfermline Athletic | - | Heart of Midlothian | 1:2 |
Spain