| 6. Round | 22/09/2021 | Espanyol Barcelona | - | CD Alavés | 1:0 | ||||
| 7. Round | 25/09/2021 | CD Alavés | - | Atlético Madrid | 1:0 | ||||
| 18. Round | 18/12/2021 | Rayo Vallecano | - | CD Alavés | 2:0 |  |
|||
| 4. Round | 21/12/2021 | Villarreal CF | - | CD Alavés | 5:2 | ||||
| 21. Round | 18/01/2022 | Real Betis | - | CD Alavés | 4:0 |
| Alberto Rodríguez Baró | |
| Born: | 10.09.1997 |
| Place of birth: |
Fuenlabrada, 
Spain |
| Nationality: |
Spain
|
| Height: | 184 cm |
| Weight: | 71 kg |
| Position(s): | Centre Back Central Midfielder |
| Foot: | right |
