| 15. Round | 27/01/2024 | Sporting de Huelva [Women] | - | Villarreal CF [Women] | 0:1 | ||||
| 17. Round | 10/02/2024 | Valencia CF [Women] | - | Villarreal CF [Women] | 0:1 | ||||
| 18. Round | 17/02/2024 | Villarreal CF [Women] | - | Real Sociedad [Women] | 1:1 | ||||
| 19. Round | 09/03/2024 | Costa Adeje Tenerife [Women] | - | Villarreal CF [Women] | 1:1 | ||||
| 20. Round | 16/03/2024 | Villarreal CF [Women] | - | Madrid CFF [Women] | 1:4 | ||||
| 21. Round | 24/03/2024 | Levante Las Planas [Women] | - | Villarreal CF [Women] | 1:1 | ||||
| 23. Round | 13/04/2024 | FC Barcelona [Women] | - | Villarreal CF [Women] | 5:1 | ||||
| 26. Round | 04/05/2024 | Athletic Club [Women] | - | Villarreal CF [Women] | 1:0 | ||||
| 27. Round | 10/05/2024 | Villarreal CF [Women] | - | SD Eibar [Women] | 1:1 | ||||
| 29. Round | 09/06/2024 | Villarreal CF [Women] | - | Sporting de Huelva [Women] | 2:0 |  |
|||
| 30. Round | 15/06/2024 | Atlético Madrid [Women] | - | Villarreal CF [Women] | 1:0 |  |
Brazil