| 2. Round | 10/09/2006 | Real Betis | - | Athletic Club | 3:0 |  |
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| 3. Round | 17/09/2006 | Athletic Club | - | Atlético Madrid | 1:4 | ||||
| 36. Round | 27/05/2007 | Athletic Club | - | RCD Mallorca | 1:0 | ||||
| 37. Round | 09/06/2007 | Villarreal CF | - | Athletic Club | 3:1 | ||||
| 38. Round | 17/06/2007 | Athletic Club | - | Levante UD | 2:0 | |
Spain