| 1. Round | 29/09/1999 | MKE Ankaragücü | - | Atlético Madrid | 1:0 | ||||
| 3. Round | 22/11/1999 | VfL Wolfsburg | - | Atlético Madrid | 2:3 | ||||
| Round of 16 | 01/03/2000 | Atlético Madrid | - | RC Lens | 2:2 |
| 1. Round | 29/09/1999 | MKE Ankaragücü | - | Atlético Madrid | 1:0 | ||||
| 3. Round | 22/11/1999 | VfL Wolfsburg | - | Atlético Madrid | 2:3 | ||||
| Round of 16 | 01/03/2000 | Atlético Madrid | - | RC Lens | 2:2 |
| Antonio Muñoz Gómez | |
| Born: | 04.02.1968 |
| Place of birth: |
Córdoba, 
Spain |
| Nationality: |
Spain
|
| Height: | 175 cm |
| Weight: | 74 kg |
| Position(s): | Left Back |