| 2. Round | 15/09/2024 | Madrid CFF [Women] | - | Espanyol Barcelona [Women] | 2:1 | ||||
| 3. Round | 22/09/2024 | Espanyol Barcelona [Women] | - | Costa Adeje Tenerife [Women] | 0:0 | ||||
| 4. Round | 28/09/2024 | Real Betis [Women] | - | Espanyol Barcelona [Women] | 0:0 | ||||
| 5. Round | 06/10/2024 | Espanyol Barcelona [Women] | - | SD Eibar [Women] | 2:1 | ||||
| 17. Round | 31/01/2025 | Real Madrid [Women] | - | Espanyol Barcelona [Women] | 5:0 | ||||
| 19. Round | 16/02/2025 | Granada CF [Women] | - | Espanyol Barcelona [Women] | 2:1 | ||||
| 20. Round | 02/03/2025 | Espanyol Barcelona [Women] | - | Deportivo La Coruña [Women] | 1:1 | ||||
| 21. Round | 08/03/2025 | Espanyol Barcelona [Women] | - | Madrid CFF [Women] | 3:3 |  |
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| 22. Round | 16/03/2025 | Atlético Madrid [Women] | - | Espanyol Barcelona [Women] | 1:1 | ||||
| 24. Round | 29/03/2025 | Costa Adeje Tenerife [Women] | - | Espanyol Barcelona [Women] | 4:1 | ||||
| 27. Round | 26/04/2025 | SD Eibar [Women] | - | Espanyol Barcelona [Women] | 1:1 | ||||
| 28. Round | 03/05/2025 | Espanyol Barcelona [Women] | - | Real Sociedad [Women] | 0:3 | ||||
| 29. Round | 11/05/2025 | Athletic Club [Women] | - | Espanyol Barcelona [Women] | 1:0 |
Jamaica