| 7. Round | 19/09/2024 | CD Leganés | - | Athletic Club | 0:2 | ||||
| 8. Round | 29/09/2024 | Athletic Club | - | Sevilla FC | 1:1 | ||||
| 10. Round | 19/10/2024 | Athletic Club | - | Espanyol Barcelona | 4:1 |  |
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| 27. Round | 09/03/2025 | Athletic Club | - | RCD Mallorca | 1:1 | ||||
| 28. Round | 16/03/2025 | Sevilla FC | - | Athletic Club | 0:1 | |
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| 29. Round | 30/03/2025 | Athletic Club | - | CA Osasuna | 0:0 | |
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| 30. Round | 06/04/2025 | Villarreal CF | - | Athletic Club | 0:0 | ||||
| 32. Round | 20/04/2025 | Real Madrid | - | Athletic Club | 1:0 | |
Spain