| 1. Round | 23/09/1945 | Real Madrid | - | Athletic Club | 1:1 |  |
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| 2. Round | 30/09/1945 | Athletic Club | - | Valencia CF | 2:2 | ||||
| 4. Round | 14/10/1945 | Athletic Club | - | Real Oviedo | 2:4 | ||||
| 19. Round | 10/02/1946 | Hércules CF | - | Athletic Club | 0:0 | ||||
| 25. Round | 24/03/1946 | CD Alcoyano | - | Athletic Club | 3:2 | ||||
| 26. Round | 31/03/1946 | Athletic Club | - | Atlético Aviación | 0:2 |
Spain