| 2. Round | 21/08/2022 | Athletic Club | - | Valencia CF | 1:0 | ||||
| 4. Round | 04/09/2022 | Athletic Club | - | Espanyol Barcelona | 0:1 |  |
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| 11. Round | 23/10/2022 | FC Barcelona | - | Athletic Club | 4:0 | ||||
| 12. Round | 30/10/2022 | Athletic Club | - | Villarreal CF | 1:0 | ||||
| 13. Round | 04/11/2022 | Girona FC | - | Athletic Club | 2:1 | ||||
| 14. Round | 08/11/2022 | Athletic Club | - | Real Valladolid | 3:0 | |
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| 24. Round | 05/03/2023 | Rayo Vallecano | - | Athletic Club | 0:0 | ||||
| 30. Round | 22/04/2023 | UD Almería | - | Athletic Club | 1:2 | ||||
| 31. Round | 27/04/2023 | Athletic Club | - | Sevilla FC | 0:1 | ||||
| 38. Round | 04/06/2023 | Real Madrid | - | Athletic Club | 1:1 |
Spain