| 1. Round | 05/09/2021 | Sporting de Huelva [Women] | - | Villarreal CF [Women] | 0:0 | ||||
| 3. Round | 25/09/2021 | CD Alavés [Women] | - | Villarreal CF [Women] | 2:0 | ||||
| 4. Round | 29/09/2021 | Villarreal CF [Women] | - | FC Barcelona [Women] | 0:8 | ||||
| 5. Round | 03/10/2021 | Real Sociedad [Women] | - | Villarreal CF [Women] | 4:0 | ||||
| 7. Round | 17/10/2021 | Athletic Club [Women] | - | Villarreal CF [Women] | 2:1 | ||||
| 13. Round | 12/12/2021 | Levante UD [Women] | - | Villarreal CF [Women] | 1:2 | ||||
| 14. Round | 18/12/2021 | Villarreal CF [Women] | - | Valencia CF [Women] | 0:2 | ||||
| 19. Round | 29/01/2022 | Villarreal CF [Women] | - | Real Sociedad [Women] | 1:4 | ||||
| 20. Round | 02/02/2022 | Sevilla FC [Women] | - | Villarreal CF [Women] | 0:3 | ||||
| 21. Round | 06/02/2022 | Villarreal CF [Women] | - | Rayo Vallecano [Women] | 1:0 | ||||
| 22. Round | 13/02/2022 | UDG Tenerife Sur [Women] | - | Villarreal CF [Women] | 3:1 |
Happy birthday! 
Spain