| 7. Round | 03/11/1963 | FC Barcelona | - | Sevilla FC | 6:0 | ||||
| 8. Round | 10/11/1963 | Levante UD | - | FC Barcelona | 4:5 | ||||
| 9. Round | 17/11/1963 | FC Barcelona | - | Real Oviedo | 2:1 | ||||
| 13. Round | 22/12/1963 | FC Barcelona | - | Córdoba CF | 3:1 | ||||
| 15. Round | 05/01/1964 | FC Barcelona | - | Real Betis | 4:1 | ||||
| 16. Round | 12/01/1964 | FC Barcelona | - | Valencia CF | 4:0 | ||||
| 17. Round | 19/01/1964 | Pontevedra CF | - | FC Barcelona | 0:2 | ||||
| 18. Round | 26/01/1964 | FC Barcelona | - | Real Murcia | 4:1 | ||||
| 20. Round | 08/02/1964 | FC Barcelona | - | Real Zaragoza | 3:3 |  |
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| 21. Round | 16/02/1964 | Real Valladolid | - | FC Barcelona | 2:0 | ||||
| 22. Round | 23/02/1964 | Sevilla FC | - | FC Barcelona | 1:1 | ||||
| 23. Round | 01/03/1964 | FC Barcelona | - | Levante UD | 6:2 | |
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| 25. Round | 15/03/1964 | Real Oviedo | - | FC Barcelona | 2:1 | ||||
| 24. Round | 18/03/1964 | FC Barcelona | - | Athletic Club | 2:1 | ||||
| 27. Round | 30/03/1964 | FC Barcelona | - | Real Madrid | 1:2 | ||||
| 30. Round | 25/04/1964 | Real Betis | - | FC Barcelona | 2:3 |
Spain