| 1. Round | 05/09/1965 | FC Barcelona | - | RCD Mallorca | 3:1 | ||||
| 2. Round | 12/09/1965 | CE Sabadell | - | FC Barcelona | 1:3 | ||||
| 5. Round | 03/10/1965 | FC Barcelona | - | Valencia CF | 1:2 | ||||
| 9. Round | 14/11/1965 | FC Barcelona | - | Real Zaragoza | 0:1 | ||||
| 10. Round | 21/11/1965 | Elche CF | - | FC Barcelona | 1:0 |
Spain