| 1. Round | 05/09/2021 | Real Sociedad [Women] | - | Valencia CF [Women] | 4:1 | ||||
| 8. Round | 31/10/2021 | FC Barcelona [Women] | - | Real Sociedad [Women] | 8:1 | ||||
| 18. Round | 09/02/2022 | Real Sociedad [Women] | - | FC Barcelona [Women] | 1:9 | ||||
| 24. Round | 12/03/2022 | Real Betis [Women] | - | Real Sociedad [Women] | 0:3 |
Spain