| 3. Round | 17/09/1993 | Real Valladolid | - | Sevilla FC | 2:2 | ||||
| 4. Round | 25/09/1993 | Real Sociedad | - | Real Valladolid | 1:0 | ||||
| 6. Round | 06/10/1993 | FC Barcelona | - | Real Valladolid | 3:0 | ||||
| 7. Round | 17/10/1993 | Real Valladolid | - | Real Zaragoza | 0:0 | ||||
| 9. Round | 30/10/1993 | Athletic Club | - | Real Valladolid | 3:0 | ||||
| 10. Round | 06/11/1993 | Real Valladolid | - | Deportivo La Coruña | 0:0 | ||||
| 11. Round | 09/11/1993 | Real Oviedo | - | Real Valladolid | 1:0 | ||||
| 12. Round | 20/11/1993 | Real Valladolid | - | Atlético Madrid | 1:1 |  |
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| 13. Round | 27/11/1993 | Racing Santander | - | Real Valladolid | 5:1 |
Argentina