| 1. Round | 10/11/1999 | Villarreal CF | - | CD Leganés | 0:1 |  |
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| 2. Round | 11/01/2000 | Villarreal CF | - | Barakaldo CF | 1:0 | ||||
| Round of 16 | 19/01/2000 | SD Compostela | - | Villarreal CF | 3:0 | ||||
| Round of 16 | 01/02/2000 | Villarreal CF | - | SD Compostela | 2:4 pso |
| 1. Round | 10/11/1999 | Villarreal CF | - | CD Leganés | 0:1 | |
|||
| 2. Round | 11/01/2000 | Villarreal CF | - | Barakaldo CF | 1:0 | ||||
| Round of 16 | 19/01/2000 | SD Compostela | - | Villarreal CF | 3:0 | ||||
| Round of 16 | 01/02/2000 | Villarreal CF | - | SD Compostela | 2:4 pso |
| Javier Jiménez Santafé | |
| Born: | 21.01.1979 |
| Place of birth: |
Santa Coloma, 
Spain |
| Nationality: |
Spain
|
| Height: | 176 cm |
| Weight: | 72 kg |
| Position(s): | Right Midfielder |
| Foot: | right |