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| 1st(1st leg) | Botafogo - RJ | - | Avai - SC | 2:0 (1:0) | ||
| 2nd (2nd leg) | Avai - SC | - | Botafogo - RJ | 1:0 (1:0) | ||
| 1st(1st leg): 30/05/2021 20:00 | 2nd (2nd leg): 06/06/2021 20:00 | Winner: Botafogo - RJ | ||||
| 1st(1st leg) | Internacional | - | Coritiba - PR | 1:1 (0:0) | ||
| 2nd (2nd leg) | Coritiba - PR | - | Internacional | 3:2 (2:1) | ||
| 1st(1st leg): 31/05/2021 19:15 | 2nd (2nd leg): 04/06/2021 19:15 | Winner: Coritiba - PR | ||||
