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| 1st(1st leg) | Audax Italiano | - | Colo-Colo | 0:2 (0:2) | ||
| 2nd (2nd leg) | Colo-Colo | - | Audax Italiano | 4:5 (2:1) | ||
| 1st(1st leg): 20/11/2012 21:00 | 2nd (2nd leg): 24/11/2012 23:00 | Winner: Colo-Colo | ||||
| 1st(1st leg) | Huachipato | - | Palestino | 1:1 (0:1) | ||
| 2nd (2nd leg) | Palestino | - | Huachipato | 1:2 (0:1) | ||
| 1st(1st leg): 20/11/2012 23:30 | 2nd (2nd leg): 24/11/2012 20:45 | Winner: Huachipato | ||||
| 1st(1st leg) | Unión Española | - | Universidad de Chile | 0:0 (0:0) | ||
| 2nd (2nd leg) | Universidad de Chile | - | Unión Española | 1:4 (1:0) | ||
| 1st(1st leg): 21/11/2012 22:00 | 2nd (2nd leg): 25/11/2012 20:45 | Winner: Unión Española | ||||
| 1st(1st leg) | Rangers | - | Deportes Iquique | 1:0 (0:0) | ||
| 2nd (2nd leg) | Deportes Iquique | - | Rangers | 0:1 (0:0) | ||
| 1st(1st leg): 22/11/2012 00:15 | 2nd (2nd leg): 25/11/2012 23:00 | Winner: Rangers | ||||
