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| 1st(1st leg) | Caracas FC | - | Santos FC | 2:2 (0:1) | ||
| 2nd (2nd leg) | Santos FC | - | Caracas FC | 3:2 (2:2) | ||
| 1st(1st leg): 02/05/2007 21:15 | 2nd (2nd leg): 10/05/2007 22:30 | Winner: Santos FC | ||||
| 1st(1st leg) | CF América | - | Colo-Colo | 3:0 (2:0) | ||
| 2nd (2nd leg) | Colo-Colo | - | CF América | 2:1 (0:0) | ||
| 1st(1st leg): 02/05/2007 23:30 | 2nd (2nd leg): 09/05/2007 00:45 | Winner: CF América | ||||
| 1st(1st leg) | Defensor Sporting | - | Flamengo RJ | 3:0 (1:0) | ||
| 2nd (2nd leg) | Flamengo RJ | - | Defensor Sporting | 2:0 (1:0) | ||
| 1st(1st leg): 03/05/2007 01:45 | 2nd (2nd leg): 10/05/2007 01:45 | Winner: Defensor Sporting | ||||
| 1st(1st leg) | São Paulo FC | - | Grêmio Porto Alegre | 1:0 (0:0) | ||
| 2nd (2nd leg) | Grêmio Porto Alegre | - | São Paulo FC | 2:0 (1:0) | ||
| 1st(1st leg): 03/05/2007 01:45 | 2nd (2nd leg): 10/05/2007 01:45 | Winner: Grêmio Porto Alegre | ||||
| 1st(1st leg) | Boca Juniors | - | Vélez Sarsfield | 3:0 (1:0) | ||
| 2nd (2nd leg) | Vélez Sarsfield | - | Boca Juniors | 3:1 (2:1) | ||
| 1st(1st leg): 03/05/2007 01:45 | 2nd (2nd leg): 09/05/2007 23:15 | Winner: Boca Juniors | ||||
| 1st(1st leg) | Paraná Clube | - | Libertad | 1:2 (0:0) | ||
| 2nd (2nd leg) | Libertad | - | Paraná Clube | 1:1 (1:0) | ||
| 1st(1st leg): 03/05/2007 23:00 | 2nd (2nd leg): 11/05/2007 01:00 | Winner: Libertad | ||||
| 1st(1st leg) | Nacional | - | Club Necaxa | 3:2 (2:1) | ||
| 2nd (2nd leg) | Club Necaxa | - | Nacional | 0:1 (0:0) | ||
| 1st(1st leg): 04/05/2007 01:15 | 2nd (2nd leg): 11/05/2007 03:30 | Winner: Nacional | ||||
| 1st(1st leg) | Cúcuta Deportivo | - | Deportivo Toluca | 5:1 (4:1) | ||
| 2nd (2nd leg) | Deportivo Toluca | - | Cúcuta Deportivo | 2:0 (1:0) | ||
| 1st(1st leg): 04/05/2007 03:30 | 2nd (2nd leg): 09/05/2007 03:15 | Winner: Cúcuta Deportivo | ||||
