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| 1st(1st leg) | Racing Ferrol | - | CD Toledo | 2:3 | ||
| 2nd (2nd leg) | CD Toledo | - | Racing Ferrol | 1:1 | ||
| 1st(1st leg): 25/10/1994 | 2nd (2nd leg): 08/11/1994 | Winner: CD Toledo | ||||
| 1st(1st leg) | Benidorm CD | - | CD Badajoz | 1:0 | ||
| 2nd (2nd leg) | CD Badajoz | - | Benidorm CD | 2:0 | ||
| 1st(1st leg): 25/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: CD Badajoz | ||||
| 1st(1st leg) | Caudal Deportivo | - | Villarreal CF | 1:0 | ||
| 2nd (2nd leg) | Villarreal CF | - | Caudal Deportivo | 3:0 | ||
| 1st(1st leg): 25/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: Villarreal CF | ||||
| 1st(1st leg) | Almería CF | - | CD Lugo | 2:0 | ||
| 2nd (2nd leg) | CD Lugo | - | Almería CF | 3:0 | ||
| 1st(1st leg): 25/10/1994 | 2nd (2nd leg): 08/11/1994 | Winner: CD Lugo | ||||
| 1st(1st leg) | CD Leonesa | - | CDC Moscardó | 2:1 | ||
| 2nd (2nd leg) | CDC Moscardó | - | CD Leonesa | 0:1 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: CD Leonesa | ||||
| 1st(1st leg) | Córdoba CF | - | CA Osasuna | 2:1 | ||
| 2nd (2nd leg) | CA Osasuna | - | Córdoba CF | 3:0 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: CA Osasuna | ||||
| 1st(1st leg) | UD Las Palmas | - | CD Ourense | 3:0 | ||
| 2nd (2nd leg) | CD Ourense | - | UD Las Palmas | 2:2 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: UD Las Palmas | ||||
| 1st(1st leg) | Recreativo Huelva | - | Getafe CF | 1:1 | ||
| 2nd (2nd leg) | Getafe CF | - | Recreativo Huelva | 2:1 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: Getafe CF | ||||
| 1st(1st leg) | Granada CF | - | UD Salamanca | 0:2 | ||
| 2nd (2nd leg) | UD Salamanca | - | Granada CF | 2:0 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: UD Salamanca | ||||
| 1st(1st leg) | Mármol Macael CD | - | RCD Mallorca | 0:2 | ||
| 2nd (2nd leg) | RCD Mallorca | - | Mármol Macael CD | 2:1 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: RCD Mallorca | ||||
| 1st(1st leg) | UE Figueres | - | Ontinyent CF | 0:1 | ||
| 2nd (2nd leg) | Ontinyent CF | - | UE Figueres | 2:0 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: Ontinyent CF | ||||
| 1st(1st leg) | CD Manchego | - | CD Leganés | 2:4 | ||
| 2nd (2nd leg) | CD Leganés | - | CD Manchego | 4:2 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: CD Leganés | ||||
| 1st(1st leg) | CD Alcoyano | - | Palamós CF | 1:0 | ||
| 2nd (2nd leg) | Palamós CF | - | CD Alcoyano | 3:1 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: Palamós CF | ||||
| 1st(1st leg) | Real Murcia | - | UP Langreo | 0:0 | ||
| 2nd (2nd leg) | UP Langreo | - | Real Murcia | 0:2 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 08/11/1994 | Winner: Real Murcia | ||||
| 1st(1st leg) | CF Fuenlabrada | - | Gimnàstic de Tarragona | 0:1 | ||
| 2nd (2nd leg) | Gimnàstic de Tarragona | - | CF Fuenlabrada | 3:0 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: Gimnàstic de Tarragona | ||||
| 1st(1st leg) | Cádiz CF | - | FC Andorra | 0:1 | ||
| 2nd (2nd leg) | FC Andorra | - | Cádiz CF | 2:2 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: FC Andorra | ||||
| 1st(1st leg) | CD Corralejo | - | Atlético Marbella | 2:0 | ||
| 2nd (2nd leg) | Atlético Marbella | - | CD Corralejo | 5:3 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: CD Corralejo | ||||
| 1st(1st leg) | AEC Manlleu | - | UE Lleida | 1:0 | ||
| 2nd (2nd leg) | UE Lleida | - | AEC Manlleu | 3:1 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: UE Lleida | ||||
| 1st(1st leg) | Utebo FC | - | CF Extremadura | 3:6 | ||
| 2nd (2nd leg) | CF Extremadura | - | Utebo FC | 6:1 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: CF Extremadura | ||||
| 1st(1st leg) | Cartagena FC | - | Hércules CF | 2:0 | ||
| 2nd (2nd leg) | Hércules CF | - | Cartagena FC | 3:1 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: Cartagena FC | ||||
| 1st(1st leg) | CD Numancia | - | Rayo Vallecano | 0:2 | ||
| 2nd (2nd leg) | Rayo Vallecano | - | CD Numancia | 2:2 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: Rayo Vallecano | ||||
| 1st(1st leg) | SD Noja | - | CD Mensajero | 1:1 | ||
| 2nd (2nd leg) | CD Mensajero | - | SD Noja | 2:0 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: CD Mensajero | ||||
| 1st(1st leg) | CD Palencia | - | SD Eibar | 0:2 | ||
| 2nd (2nd leg) | SD Eibar | - | CD Palencia | 2:2 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: SD Eibar | ||||
| 1st(1st leg) | CD San Fernando | - | CP Mérida | 1:0 | ||
| 2nd (2nd leg) | CP Mérida | - | CD San Fernando | 2:0 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: CP Mérida | ||||
| 1st(1st leg) | Real Jaén | - | Yeclano CF | 0:0 | ||
| 2nd (2nd leg) | Yeclano CF | - | Real Jaén | 1:1 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: Real Jaén | ||||
| 1st(1st leg) | SD Beasain | - | CD Castellón | 0:0 | ||
| 2nd (2nd leg) | CD Castellón | - | SD Beasain | 2:2 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: SD Beasain | ||||
| 1st(1st leg) | UD SS Reyes | - | CE Sabadell | 1:0 | ||
| 2nd (2nd leg) | CE Sabadell | - | UD SS Reyes | 2:3 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: UD SS Reyes | ||||
| 1st(1st leg) | Sestao SC | - | UDA Gramenet | 1:0 | ||
| 2nd (2nd leg) | UDA Gramenet | - | Sestao SC | 0:2 | ||
| 1st(1st leg): 26/10/1994 | 2nd (2nd leg): 09/11/1994 | Winner: Sestao SC | ||||
