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| 1st(1st leg) | Recreativo Huelva | - | Villarreal CF | 1:0 (1:0) | ||
| 2nd (2nd leg) | Villarreal CF | - | Recreativo Huelva | 2:0 (1:0, 1:0, 2:0) aet | ||
| 1st(1st leg): 09/01/2008 19:00 | 2nd (2nd leg): 16/01/2008 19:00 | Winner: Villarreal CF | ||||
| 1st(1st leg) | Real Zaragoza | - | Racing Santander | 1:1 (1:0) | ||
| 2nd (2nd leg) | Racing Santander | - | Real Zaragoza | 4:2 (2:1) | ||
| 1st(1st leg): 09/01/2008 19:00 | 2nd (2nd leg): 16/01/2008 19:00 | Winner: Racing Santander | ||||
| 1st(1st leg) | Athletic Club | - | Espanyol Barcelona | 1:1 (0:0) | ||
| 2nd (2nd leg) | Espanyol Barcelona | - | Athletic Club | 3:4 (1:0, 1:1, 1:1) pso | ||
| 1st(1st leg): 09/01/2008 19:00 | 2nd (2nd leg): 16/01/2008 19:00 | Winner: Athletic Club | ||||
| 1st(1st leg) | Real Betis | - | Valencia CF | 1:2 (0:2) | ||
| 2nd (2nd leg) | Valencia CF | - | Real Betis | 2:1 (1:0) | ||
| 1st(1st leg): 09/01/2008 19:00 | 2nd (2nd leg): 16/01/2008 21:00 | Winner: Valencia CF | ||||
| 1st(1st leg) | Getafe CF | - | Levante UD | 3:0 (1:0) | ||
| 2nd (2nd leg) | Levante UD | - | Getafe CF | 0:1 (0:0) | ||
| 1st(1st leg): 09/01/2008 19:00 | 2nd (2nd leg): 16/01/2008 19:00 | Winner: Getafe CF | ||||
| 1st(1st leg) | Sevilla FC | - | FC Barcelona | 1:1 (1:1) | ||
| 2nd (2nd leg) | FC Barcelona | - | Sevilla FC | 0:0 (0:0) | ||
| 1st(1st leg): 09/01/2008 21:00 | 2nd (2nd leg): 15/01/2008 20:00 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Atlético Madrid | - | Real Valladolid | 0:0 (0:0) | ||
| 2nd (2nd leg) | Real Valladolid | - | Atlético Madrid | 1:1 (0:0) | ||
| 1st(1st leg): 10/01/2008 19:00 | 2nd (2nd leg): 16/01/2008 19:00 | Winner: Atlético Madrid | ||||
| 1st(1st leg) | RCD Mallorca | - | Real Madrid | 2:1 (1:1) | ||
| 2nd (2nd leg) | Real Madrid | - | RCD Mallorca | 0:1 (0:0) | ||
| 1st(1st leg): 10/01/2008 21:00 | 2nd (2nd leg): 16/01/2008 20:00 | Winner: RCD Mallorca | ||||
