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| 03/01/2025 | 18:00 | Pontevedra CF | - | RCD Mallorca | 3:0 (1:0) | |
| 18:00 | Granada CF | - | Getafe CF | 0:1 (0:0, 0:0, 0:1) aet | ||
| 18:00 | Racing Ferrol | - | Rayo Vallecano | 1:3 (0:2) | ||
| 04/01/2025 | 14:30 | SD Huesca | - | Real Betis | 0:1 (0:1) | |
| 15:30 | CD Tenerife | - | CA Osasuna | 1:2 (1:2) | ||
| 16:30 | UD Almería | - | Sevilla FC | 4:1 (0:1) | ||
| 18:00 | UD Barbastro | - | FC Barcelona | 0:4 (0:2) | ||
| 20:30 | UD Logroñés | - | Athletic Club | 3:4 (0:0, 0:0, 0:0) pso | ||
| 20:30 | Marbella FC | - | Atlético Madrid | 0:1 (0:1) | ||
| 05/01/2025 | 11:00 | Ourense CF | - | Real Valladolid | 3:2 (2:2) | |
| 11:00 | Elche CF | - | UD Las Palmas | 4:0 (1:0) | ||
| 14:30 | SD Ponferradina | - | Real Sociedad | 0:2 (0:0) | ||
| 14:30 | Racing Santander | - | RC Celta | 2:3 (1:1) | ||
| 14:30 | FC Cartagena | - | CD Leganés | 1:2 (1:1) | ||
| 06/01/2025 | 18:00 | Deportiva Minera | - | Real Madrid | 0:5 (0:3) | |
| 07/01/2025 | 20:00 | CD Eldense | - | Valencia CF | 0:2 (0:2) |
