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| 1st(1st leg) | Caudal Deportivo | - | CE L'Hospitalet | 1:0 | ||
| 2nd (2nd leg) | CE L'Hospitalet | - | Caudal Deportivo | 2:0 | ||
| 1st(1st leg): 08/06/2013 18:45 | 2nd (2nd leg): 15/06/2013 18:45 | Winner: CE L'Hospitalet | ||||
| 1st(1st leg) | Athletic Club B | - | Huracán CF | 2:1 | ||
| 2nd (2nd leg) | Huracán CF | - | Athletic Club B | 4:2 pso | ||
| 1st(1st leg): 09/06/2013 11:00 | 2nd (2nd leg): 16/06/2013 16:00 | Winner: Huracán CF | ||||
| 1st(1st leg) | Real Oviedo | - | SD Eibar | 1:2 | ||
| 2nd (2nd leg) | SD Eibar | - | Real Oviedo | 1:0 | ||
| 1st(1st leg): 09/06/2013 17:30 | 2nd (2nd leg): 15/06/2013 18:30 | Winner: SD Eibar | ||||
| 1st(1st leg) | Lleida Esportiu | - | Real Jaén | 1:1 | ||
| 2nd (2nd leg) | Real Jaén | - | Lleida Esportiu | 4:3 pso | ||
| 1st(1st leg): 09/06/2013 18:00 | 2nd (2nd leg): 16/06/2013 18:00 | Winner: Real Jaén | ||||
