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| 1st(1st leg) | Caudal Deportivo | - | Atlético Madrid B | 0:1 (0:0) | ||
| 2nd (2nd leg) | Atlético Madrid B | - | Caudal Deportivo | 3:0 (1:0) | ||
| 1st(1st leg): 18/05/2014 17:30 | 2nd (2nd leg): 25/05/2014 17:00 | Winner: Atlético Madrid B | ||||
| 1st(1st leg) | Algeciras CF | - | Valencia CF B | 2:3 (1:2) | ||
| 2nd (2nd leg) | Valencia CF B | - | Algeciras CF | 1:0 (0:0) | ||
| 1st(1st leg): 18/05/2014 19:00 | 2nd (2nd leg): 25/05/2014 18:00 | Winner: Valencia CF B | ||||
