Primera División   M. W D L goals
  at home 2 1 0 1 2 : 4
  Away 2 0 0 2 1 : 4
  4 1 0 3 3 : 8
overall   M. W D L goals
  at home 2 1 0 1 2 : 4
  Away 2 0 0 2 1 : 4
  Neutral Place 0 0 0 0 0 : 0
  4 1 0 3 3 : 8
Primera División
2022/2023 17. Round Villarreal CF - CD Alavés 1:0 (1:0)
2022/2023 4. Round CD Alavés - Villarreal CF 0:4 (0:1)
2021/2022 16. Round Villarreal CF - CD Alavés 3:1 (1:0)
2021/2022 3. Round CD Alavés - Villarreal CF 2:0 (1:0)

For games that were decided on penalties the score after 120 minutes will be included in the ranking