| Primera División | M. | W | D | L | goals | |||
| at home | 1 | 1 | 0 | 0 | 3 | : | 2 | |
| Away | 1 | 0 | 0 | 1 | 1 | : | 5 | |
| ∑ | 2 | 1 | 0 | 1 | 4 | : | 7 | |
| Copa del Rey | M. | W | D | L | goals | |||
| at home | 1 | 0 | 0 | 1 | 1 | : | 2 | |
| Away | 1 | 0 | 0 | 1 | 0 | : | 3 | |
| ∑ | 2 | 0 | 0 | 2 | 1 | : | 5 | |
| overall | M. | W | D | L | goals | |||
| at home | 2 | 1 | 0 | 1 | 4 | : | 4 | |
| Away | 2 | 0 | 0 | 2 | 1 | : | 8 | |
| Neutral Place | 0 | 0 | 0 | 0 | 0 | : | 0 | |
| ∑ | 4 | 1 | 0 | 3 | 5 | : | 12 | |
| Primera División | |||||
| 1931/1932 | 11. Round | Real Unión | - | Valencia CF | 3:2 (2:0) |
| 1931/1932 | 2. Round | Valencia CF | - | Real Unión | 5:1 (3:0) |
| Copa del Rey | |||||
| 2007/2008 | 4. Round | Valencia CF | - | Real Unión | 3:0 (0:0) |
| 2007/2008 | 4. Round | Real Unión | - | Valencia CF | 1:2 (1:0) |
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For games that were decided on penalties the score after 120 minutes will be included in the ranking |
Spain