| Primera División | M. | W | D | L | goals | |||
| at home | 1 | 1 | 0 | 0 | 5 | : | 1 | |
| Away | 1 | 0 | 0 | 1 | 2 | : | 3 | |
| ∑ | 2 | 1 | 0 | 1 | 7 | : | 4 | |
| Copa del Rey | M. | W | D | L | goals | |||
| at home | 1 | 1 | 0 | 0 | 3 | : | 0 | |
| Away | 1 | 1 | 0 | 0 | 2 | : | 1 | |
| ∑ | 2 | 2 | 0 | 0 | 5 | : | 1 | |
| overall | M. | W | D | L | goals | |||
| at home | 2 | 2 | 0 | 0 | 8 | : | 1 | |
| Away | 2 | 1 | 0 | 1 | 4 | : | 4 | |
| Neutral Place | 0 | 0 | 0 | 0 | 0 | : | 0 | |
| ∑ | 4 | 3 | 0 | 1 | 12 | : | 5 | |
| Primera División | |||||
| 1931/1932 | 11. Round | Real Unión | - | Valencia CF | 3:2 (2:0) |
| 1931/1932 | 2. Round | Valencia CF | - | Real Unión | 5:1 (3:0) |
| Copa del Rey | |||||
| 2007/2008 | 4. Round | Valencia CF | - | Real Unión | 3:0 (0:0) |
| 2007/2008 | 4. Round | Real Unión | - | Valencia CF | 1:2 (1:0) |
|
For games that were decided on penalties the score after 120 minutes will be included in the ranking |
Spain 
![Valencia CF [Women]](https://s.hs-data.com/bilder/wappen/mini/21351.gif?fallback=png "Valencia CF [Women]"){kind=small}
![Valencia CF [Youth]](https://s.hs-data.com/bilder/wappen/mini/14431.gif?fallback=png "Valencia CF [Youth]"){kind=small}
![Valencia CF [Youth B]](https://s.hs-data.com/bilder/wappen/mini/25522.gif?fallback=png "Valencia CF [Youth B]"){kind=small}
![Valencia CF [Youth C]](https://s.hs-data.com/bilder/wappen/mini/29014.gif?fallback=png "Valencia CF [Youth C]"){kind=small}
