| 3. Round | 25/09/1966 | FC Barcelona | - | CE Sabadell | 2:0 | ||||
| 4. Round | 02/10/1966 | Elche CF | - | FC Barcelona | 4:3 | ||||
| 6. Round | 16/10/1966 | Espanyol Barcelona | - | FC Barcelona | 2:0 | ||||
| 7. Round | 29/10/1966 | FC Barcelona | - | Granada CF | 3:0 | ||||
| 2. Round | 01/11/1966 | Atlético Madrid | - | FC Barcelona | 0:1 | ||||
| 8. Round | 06/11/1966 | Real Zaragoza | - | FC Barcelona | 0:1 | ||||
| 9. Round | 13/11/1966 | FC Barcelona | - | Sevilla FC | 5:0 | ||||
| 10. Round | 20/11/1966 | Real Madrid | - | FC Barcelona | 1:0 | ||||
| 11. Round | 27/11/1966 | FC Barcelona | - | Hércules CF | 4:1 | ||||
| 12. Round | 04/12/1966 | Athletic Club | - | FC Barcelona | 0:0 | ||||
| 13. Round | 11/12/1966 | FC Barcelona | - | UD Las Palmas | 2:1 | ||||
| 14. Round | 18/12/1966 | FC Barcelona | - | Deportivo La Coruña | 5:0 | ||||
| 15. Round | 01/01/1967 | Valencia CF | - | FC Barcelona | 3:0 |
Spain