17/09/1966 Valencia CF - UD Las Palmas 2:1 (0:1)
18/09/1966 Granada CF - Real Zaragoza 6:2 (2:1)
Córdoba CF - Deportivo La Coruña 1:0 (1:0)
CE Sabadell - Athletic Bilbao 1:0 (0:0)
Pontevedra CF - Real Madrid 0:1 (0:0)
Espanyol Barcelona - Sevilla FC 3:1 (1:1)
Elche CF - Hércules CF 4:0 (2:0)
01/11/1966 Atlético Madrid - FC Barcelona 0:1 (0:1)
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# Team M. W D L goals Dif. Pt.
1 FC Barcelona, Spain FC Barcelona 2 2 0 0 5:1 4 4:0
  Real Madrid, Spain Real Madrid 2 2 0 0 5:1 4 4:0
3 Valencia CF, Spain Valencia CF 2 2 0 0 3:1 2 4:0
4 Granada CF, Spain Granada CF 2 1 1 0 7:3 4 3:1
5 CE Sabadell, Spain CE Sabadell 2 1 1 0 1:0 1 3:1
6 Elche CF, Spain Elche CF 2 1 0 1 5:4 1 2:2
7 Espanyol Barcelona, Spain Espanyol Barcelona 2 1 0 1 3:3 0 2:2
8 Athletic Bilbao, Spain Athletic Bilbao 2 1 0 1 1:1 0 2:2
9 Real Zaragoza, Spain Real Zaragoza 2 1 0 1 4:6 -2 2:2
10 Córdoba CF, Spain Córdoba CF 2 1 0 1 2:4 -2 2:2
11 UD Las Palmas, Spain UD Las Palmas 2 0 1 1 2:3 -1 1:3
12 Pontevedra CF, Spain Pontevedra CF 2 0 1 1 0:1 -1 1:3
13 Sevilla FC, Spain Sevilla FC 2 0 1 1 1:3 -2 1:3
14 Hércules CF, Spain Hércules CF 2 0 1 1 0:4 -4 1:3
15 Atlético Madrid, Spain Atlético Madrid 2 0 0 2 0:2 -2 0:4
  Deportivo La Coruña, Spain Deportivo La Coruña 2 0 0 2 0:2 -2 0:4
Primera División
Primera División

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