| Round of 16 | 20/09/2013 | Liga de Loja | - | River Plate | 2:1 |  |
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| Round of 16 | 26/09/2013 | River Plate | - | Liga de Loja | 2:0 | |
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| Quarter-finals | 29/10/2013 | Lanús | - | River Plate | 0:0 | |
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| Quarter-finals | 06/11/2013 | River Plate | - | Lanús | 1:3 |
| Round of 16 | 20/09/2013 | Liga de Loja | - | River Plate | 2:1 | |
|||
| Round of 16 | 26/09/2013 | River Plate | - | Liga de Loja | 2:0 | |
|||
| Quarter-finals | 29/10/2013 | Lanús | - | River Plate | 0:0 | |
|||
| Quarter-finals | 06/11/2013 | River Plate | - | Lanús | 1:3 |
| Gabriel Iván Mercado | |
| Born: | 18.03.1987 |
| Place of birth: |
Puerto Madryn, Chubut, 
Argentina |
| Nationality: |
Argentina
Spain |
| Height: | 181 cm |
| Weight: | 81 kg |
| Position(s): | Right Back Centre Back |
| Foot: | right |
