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| 1st(1st leg) | Lanús | - | River Plate | 0:0 (0:0) | ||
| 2nd (2nd leg) | River Plate | - | Lanús | 1:3 (0:2) | ||
| 1st(1st leg): 29/10/2013 23:15 | 2nd (2nd leg): 06/11/2013 23:50 | Winner: Lanús | ||||
| 1st(1st leg) | São Paulo FC | - | Atlético Nacional | 3:2 (1:1) | ||
| 2nd (2nd leg) | Atlético Nacional | - | São Paulo FC | 0:0 (0:0) | ||
| 1st(1st leg): 30/10/2013 23:50 | 2nd (2nd leg): 06/11/2013 23:50 | Winner: São Paulo FC | ||||
| 1st(1st leg) | Ponte Preta | - | Vélez Sarsfield | 0:0 (0:0) | ||
| 2nd (2nd leg) | Vélez Sarsfield | - | Ponte Preta | 0:2 (0:0) | ||
| 1st(1st leg): 31/10/2013 22:15 | 2nd (2nd leg): 07/11/2013 22:45 | Winner: Ponte Preta | ||||
| 1st(1st leg) | Libertad | - | Itagüi Ditaires | 2:0 (2:0) | ||
| 2nd (2nd leg) | Itagüi Ditaires | - | Libertad | 1:0 (1:0) | ||
| 1st(1st leg): 01/11/2013 00:30 | 2nd (2nd leg): 08/11/2013 01:15 | Winner: Libertad | ||||
