| 4. Round | 27/10/2010 | Polideportivo Ejido | - | Villarreal CF | 1:1 | ||||
| 4. Round | 10/11/2010 | Villarreal CF | - | Polideportivo Ejido | 2:0 | ||||
| Round of 16 | 21/12/2010 | Valencia CF | - | Villarreal CF | 0:0 |  |
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| Round of 16 | 06/01/2011 | Villarreal CF | - | Valencia CF | 4:2 | |
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| Quarter-finals | 12/01/2011 | Villarreal CF | - | Sevilla FC | 3:3 | ||||
| Quarter-finals | 18/01/2011 | Sevilla FC | - | Villarreal CF | 3:0 |
Argentina
Spain 
