| Group C | 05/10/2021 | FC Barcelona [Women] | - | Arsenal WFC [Women] | 4:1 | ||||
| Group C | 14/10/2021 | HB Køge [Women] | - | FC Barcelona [Women] | 0:2 | ||||
| Group C | 10/11/2021 | FC Barcelona [Women] | - | 1899 Hoffenheim [Women] | 4:0 |  |
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| Group C | 17/11/2021 | 1899 Hoffenheim [Women] | - | FC Barcelona [Women] | 0:5 | |
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| Group C | 09/12/2021 | Arsenal WFC [Women] | - | FC Barcelona [Women] | 0:4 |  |
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| Quarter-finals | 22/03/2022 | Real Madrid [Women] | - | FC Barcelona [Women] | 1:3 | ||||
| Quarter-finals | 30/03/2022 | FC Barcelona [Women] | - | Real Madrid [Women] | 5:2 | ||||
| Semi-finals | 22/04/2022 | FC Barcelona [Women] | - | VfL Wolfsburg [Women] | 5:1 | ||||
| Semi-finals | 30/04/2022 | VfL Wolfsburg [Women] | - | FC Barcelona [Women] | 2:0 | ||||
| Final | 21/05/2022 | FC Barcelona [Women] | - | Olympique Lyonnais [Women] | 1:3 |
Spain