| 1. Round | 11/09/1966 | Hércules CF | - | CE Sabadell | 0:0 | ||||
| 2. Round | 18/09/1966 | Elche CF | - | Hércules CF | 4:0 | ||||
| 5. Round | 09/10/1966 | Hércules CF | - | Granada CF | 2:1 | ||||
| 11. Round | 27/11/1966 | FC Barcelona | - | Hércules CF | 4:1 |  |
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| 12. Round | 04/12/1966 | Hércules CF | - | Deportivo La Coruña | 0:1 | ||||
| 13. Round | 11/12/1966 | Valencia CF | - | Hércules CF | 4:0 | ||||
| 28. Round | 09/04/1967 | Hércules CF | - | Valencia CF | 4:1 | ||||
| 29. Round | 16/04/1967 | Córdoba CF | - | Hércules CF | 1:1 | |
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| 30. Round | 23/04/1967 | Hércules CF | - | Atlético Madrid | 2:4 | |
Spain